Kinetics, catalysis and mechanism of methane steam reforming. Mar 18, 2014 pdrhmetal foam catalyst was studied for steam methane reforming and application to sofc fuel processing. Experiments were carried out varying the steam to methane ratio in the feed gas from 1 to 10 and. Steam reforming of natural gas on noblemetal based catalysts. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. Life cycle assessment of hydrogen production via natural gas. Use features like bookmarks, note taking and highlighting while reading production of synthesis gas by steam methane reforming. Steam methane reforming is the most common and economical way to make hydrogen.
Due to its maturity, high efficiency, and relatively low cost, steam reforming is considered a viable option for supporting a future hydrogen economy. In energy, smr is the most widely used process for the generation of hydrogen 2 if playback doesnt begin shortly, try restarting your device. The methane steam reforming reaction cannot be modeled without taking co and h. In smr, methane reacts with steam under 325 bar pressure 1 bar 14. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons.
Experiments were carried out varying the steam to methane ratio in the feed gas from 1 to 10. Steam reforming is the commonly used and mature technology for industrial hydrogen production. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high temperature, high steam to methane ratio, and low pressure to achieve maximum conversion. Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas. Methane steam reforming, methanation and watergas shift. Within such a context, this work evaluates the technical performance of a novel cmr, which utilizes two catalysts in series, rather than one. Steam methane reforming synonyms, steam methane reforming pronunciation, steam methane reforming translation, english dictionary definition of steam methane reforming.
Steam reforming of natural gas sometimes referred to as steam methane reforming smr is the most common method of producing commercial bulk hydrogen. Jul 29, 20 theory and practice of steam reforming 1. Steam methane reforming syngas production air liquide. Methane steam reforming reaction behaviour in a packed bed.
The polybed psa system adsorbs the co, co 2, and other impurities in a fixedbed adsorber at hydrogen purification uop polybed pressure swing adsorption psa systems psa systems for hydrogen production by steam reforming introduction. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. The amount of catalyst charge in the reactor was around 0. The process uses steam methane to reform a hydrocarbon feed in catalystfilled tubes heated by a topfired furnace. Methane steam reforming in industry is carried out in a catalytic multitubular fixedbed. Advanced modelling and optimisation of natural gas.
The design of the steam reforming process is in part dictated by these constraints. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Hydrogen is used in the industrial synthesis of ammonia and other chemicals. Steam methane reforming syngas production is a proven technology for producing syngas, carbon monoxide and oxogas. Redefining steam methane reformer performance in hydrogen. Methane steam reforming reaction behaviour in a packed. Water gas shift reaction and the reforming reaction. Smr is a costeffective and energy efficient way of producing hydrogen. Metal foamsupported pdrh catalyst for steam methane.
There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Thus, to achieve the benefits of the hydrogen economy, it is necessary produce hydrogen from non. In this work, we report the activity results obtained in steam methane reforming smr at 500 and 600 c using four nickelbased catalysts. Research on steam reforming technology commonly uses ch 4 as a model substance for natural gas. Low temperature methane steam reforming for hydrogen production, using experimental developed nial2o3 catalysts is studied both. Experimental studies of intrinsic kinetics and diffusion during methane steam reforming kaihu hou department of chemistry and applied chemistry science research institute university of salford, salford, uk a thesis submitted for the degree of doctor of philosophy, may 1998. Methane steam reforming is the key reaction to produce synthesis gas and hydrogen at the industrial scale. Many research and development programs are investigating the development of steam methane reforming technologies to enable the transition to sustainable energy, because it is.
Also, a 2008 iea report estimated the global annual hydrogen production in 2005 at 65 mt, with 48% from smr. Al 2 o 3 and nisio 2, prepared by incipient wetness impregnation method and b niznal and nimgal, prepared by coprecipitation method. Steam methane reforming has been a conventional process. Pdf steam methane reforming of natural gas with substantial. The effects of reaction parameters, including reaction temperature and space velocity, on hydrogen production via steam reforming of methane srm were investigated using lab and benchscale. Smr based plants are most commonly used to produce a hydrogen product or a combination of a hydrogen stream and. Steam methane reforming market global industry analysis. Carbon formation and active site of alumina supported. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. Sulfur deactivation effects on catalytic steam reforming. The overall gwp of the system is 11,888 g co2equivalentkg of hydrogen produced. Life cycle assessment of hydrogen production via natural gas steam reforming. The steam methane reforming process can be broken down into five distinct steps. It represents the eiga contribution to the refineries bref1 being organized by the european ippc2 bureau.
Steam methane reforming definition of steam methane. Topsoe offers several types of reforming technologies and has. Methane steam reforming consists in the reaction of methane and steam on a supported nickel catalyst to produce a mixture of h 2, co, co 2 and ch 4. Currently, this process is the main route to obtain hydrogen and synthesis gas for ammonia and methanol. Pdrhmetal foam catalyst was studied for steam methane reforming and application to sofc fuel processing. Steam methane reforming smr is currently the main hydrogen production process in industry, but it has high emissions of co 2, at almost 7 kg co 2 kg h 2 on average, and is responsible for about 3% of global industrial sector co 2 emissions. The expanding hydrogen generation industry as emerged as a crucial driver of the global steam methane reformers market, considering steam methane reforming has remained the most economical method of producing hydrogen. Combined steam reforming and partial oxidation of methane. Smr based plants are most commonly used to produce a hydrogen product or a combination of a hydrogen stream and another syngas product. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. C2pt catalyst process technology by gerard b hawkins managing director 2. H hiblot, i zieglerdevin, r fournet, pierrealexandre glaude. In all of the samples, the nickel load ranged between 7% and 9%.
Advanced modelling and optimisation of natural gas reforming. Steam reforming of methane is the main industrial route to produce hydrogen and synthesis gas a mixture of hydrogen and carbon monoxide syngas, or synthesis gas, is a fuel gas mixture consisting primarily of hydrogen, carbon monoxide, and very often some carbon dioxide. Steam reforming of methane, ethane, propane, and butane as single components as well as of a real gas mixture is studied to develop and evaluate a multistep surface reaction mechanism. A large number of detailed reaction mechanisms were considered. Methane steam reforming an overview sciencedirect topics. Catalytic steam reforming of methanol to produce hydrogen on supported metal catalysts.
Leaving the shift reactor, the gas contains approximately 75 vol% hydrogen, with carbon dioxide, carbon monoxide and some unconverted methane plus nitrogen if this was present in the feed to the. Contents steam reforming reactions steam reforming catalyst equilibrium considerations carbon formation poisoning steam reformer modelling pre. Life cycle assessment of hydrogen production via natural. Single step compact steam methane reforming process for hydrogencng hcng production from natural gas badhe r.
The gas produced by the steam reforming reaction first passes through a shift reactor, where carbon monoxide converts to carbon dioxide and hydrogen. Steam methane reforming hydrogen production air liquide. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. Steam methane reforming primarily involves two reactions. The resultants of the reaction include hydrogen, carbon monoxide and. According to a life cycle assessment of global hydrogen production, about 75% of worlds total hydrogen is produced by steam methane reforming.
Advanced steadystate modelling and optimisation of natural gas reforming reactors. Autothermal reforming at low steamtocarbon ratio the majority of the worlds syngasproducing plants apply steam methane reforming, with the specific type of reforming technology depending on application and operating conditions. Kinetics of steam reforming over a nialumina catalyst. The reactor employed for the study was made of 7 mm i. Distributed hydrogen production via steam methane reforming. Pdf steam methane reforming has been a conventional process to produce synthesis gas which is an important feedstock to many chemicals. Palladiumbased catalytic membrane reactors cmrs effectively remove h 2 to induce higher conversions in methane steam reforming msr and watergasshift reactions wgs. Combined steam reforming and partial oxidation of methane to synthesis gas under electrical discharge korada supat and sumaeth chavadej the petroleum and petrochemical college, chulalongkorn university, bangkok 10330, thailand.
In steammethane reforming, methane reacts with steam under 325 bar pressure 1 bar 14. Steam reforming of methane over a commercially available, nickelalumina catalyst was experimentally studied. Production of synthesis gas by steam methane reforming. Videos you watch may be added to the tvs watch history and. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. Combined steam reforming and partial oxidation of methane to. Advanced steadystate modelling and optimisation of natural gas reforming reactors vasco hugo coimbra manacas dissertation to obtain the master of science degree in chemical engineering examination committee chairperson. Catalytic steam reforming of methanol to produce hydrogen on supported metal catalysts, hydrogen energy challenges and perspectives, dragica. Steam reforming of methane in a synthesis gas from biomass gasification h hiblot, i zieglerdevin, r fournet, pierrealexandre glaude to cite this version. Pdf benchscale steam reforming of methane for hydrogen. Catalytic steam reforming of methanol to produce hydrogen on.
Contents steam reforming reactions steam reforming catalyst equilibrium considerations carbon formation poisoning steam reformer modelling preand post reforming 3. The advantages of distributed hydrogen production are the production unit can be located at the consumer refueling site, the unit capacity can be tailored to the sites fueling requirements, and this approach eliminates the need for an extensive hydrogen delivery infrastructure. Steam methane reforming of natural gas with substantial carbon dioxide contents process optimization for gastoliquid applications. Water enters the furnace, producing steam at a very high temperature. Effect of pressure, temperature and steam to carbon ratio. Introduction the steam methane reforming process is the most widespread method for the hydrogen production. Steam reforming of natural gas wikid energy funhouse. Methane steam reforming kinetics for a rhodiumbased. Intrinsic kinetics intrinsic rate equations were derived for the steam reforming of methane, accompanied by watergas shift on a ni mga1204 catalyst. Steammethane reforming at low temperature on nickelbased.
Life cycle assessment of hydrogen production via natural gas steam reforming revised february 2001 l nreltp57027637 pamela l. The resultants of the reaction include hydrogen, carbon monoxide and a relatively small amount of carbon dioxide. Steam reforming of methane in a synthesis gas from biomass. However, steam reforming of methane does not reduce the use of fossil fuels and it still releases carbon to the environment in the form of co 2. Methane steam reforming is a wellestablished process as shown in fig. Assessment of co2 capture options from various points in. Comparison of catalyst geometries for methane steam reforming. Effect of pressure, temperature and steam to carbon ratio on. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. International journal of hydrogen energy, elsevier. Uops polybed psa system produces the highpurity hydrogen needed for the optimum performance of catalytic processes.
Steam methane reforming is a widelyused process to convert methane into a mixture of hydrogen and carbon monoxide syngas. Download it once and read it on your kindle device, pc, phones or tablets. Steam reforming of natural gas on noblemetal based. Steam reforming is endothermicthat is, heat must be supplied to the process for the reaction to proceed.
Introduction an efficient and reliable way to produce hydrogen gas. Comparison of catalyst geometries for methane steam. Pdf analysis on operating parameter design to steam methane. In addition to the maturity of the technology, natural gas reforming is also the most economical among all hydrogen production pathways. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and. The steam methane reformer is widely used in industry. This study aims at systematically determining the effect of temperature 400oc, pressure 120 bar and sc ratio 39 on the vegetable oils steam reforming process. Smr is a costeffective and energy efficient way of producing. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Hydrogen production from dry reforming of methane has attracted considerable attention in recent years 6, due to the capability of the process to. May 14, 2010 steammethane reforming is a process in which high temperature steam 700c c is reacted with a methane source usually natural gas at a high pressure of 325 bar with a catylist. Steam reforming of methane in a synthesis gas from biomass gasification. Sulfur deactivation effects on catalytic steam reforming of methane produced by biomass gasification parham 2sadooghi1, reinhard rauch 1,2vienna university of technology getreidemarkt 9166 vienna 1060 austria, email. Steam methane reforming smr is a process in which methane from natural gas is heated, with steam and a catalyst, to produce synthetic fuel.
Hydrogen production steam methane reforming smr pdf, hydrogen fact sheet, archived from the original pdf on 4 february 2006. Introduction an efficient and reliable way to produce hydrogen gas is to reform the available natural gas fuel. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Natural gas reforming, steam methane reforming, autothermal reforming, gproms, modelling, optimisation.
Integration of methane steam reforming and water gas shift. Methane steam reforming reaction behaviour in a packed bed membrane reactor lemnouer chibane and brahim djellouli international journal of chemical engineering and applications, vol. Distributed production of hydrogen from natural gas utilizes small scale steam methane reforming technology. Home processing solutions gas synthesis gas treating steam methane reforming. Catalytic steam reforming of methanol to produce hydrogen. Kjersti omdahl christensen steam reforming of methane on. Hydrogen from natural gas via steam methane reforming smr.
1359 416 1140 973 955 661 1422 209 1192 1302 1045 358 1138 598 755 1481 802 1416 566 186 236 1269 1364 753 1491 554 910 1363 893 898 1321 592